Radon-222 exhalation from open ground on and around a uranium mine in the wet-dry tropics

Radon-222 exhalation from the ground surface depends upon a number of variables such as the 226Ra activity concentration and its distribution in soil grains; soil grain size; soil porosity, temperature and moisture; atmospheric pressure, rainfall and temperature. In this study, 222Rn exhalation flux density measurements within and around the Ranger uranium mine in northern Australia were performed to investigate the effect of these variables within a tropical region. Measurements were taken at the waste rock dumps, ore stockpiles, mine pits, and at sites where effluent water with elevated 226Ra concentration has been spray irrigated over land, as well as at sites outside the mine. The sites selected represented a variety of geomorphic regions ranging from uranium-bearing rocks to ambient soils. Generally, wet season rains reduced 222Rn exhalation but at a few sites the onset of rains caused a step rise in exhalation flux densities. The results show that parameters such as 226Ra activity concentration, soil grain size and soil porosity have a marked effect on 222Rn flux densities. For similar geomorphic sites, 226Ra activity concentration is a dominant factor, but soil grain size and porosity also influence 222Rn exhalation. Surfaces with vegetation showed higher exhalation flux densities than their barren counterparts, perhaps because the associated root structure increases soil porosity and moisture retention. Repeated measurements over one year at eight sites enabled an analysis of precipitation and soil moisture effects on 222Rn exhalation. Soil moisture depth profiles varied both between seasons and at different times during the wet season, indicating that factors such as duration, intensity and time between precipitation events can influence 222Rn flux densities considerably.     

Polylactic Acid Composites Utilising Sequential Surface Treatments of Lignocellulose: Chemistry,Morphology and Properties

Polylactic acid (PLA)—maple fibre composites have been synthesised using a series of sequentially modified cellulose fibres (namely alkylation followed by either acetylation or silanation). Confirmations of the sequential modifications were made using Fourier Transform Infrared Spectroscopy and Inductively Coupled Plasma—Atomic Emission Spectroscopy and the new surface morphologies analysed using Scanning Electron Microscopy. The key advantage of the use of sequential treatments (with initial alkali treatment) was the allowance for direct grafting of suitable chemical groups onto the cellulose in the fibre due to the removal of lignin, hemicellulose and other surface impurities. However, a balance was found to exist between alkali exposure time, concentration and resulting fibre integrity. The conditions used resulted in a loss in fibre weight, fibre moisture content and tensile strength. Sequential treatments with acetylation or silane resulted in a 15–21% strength recovery from that of the alkali treated composite. Factors that influenced this recovery in strength were the improved fibre-polymer interface, namely the hydrophilic balancing of the fibres and this further affected the thermal-hydrolysis of the PLA during composite fabrication.     

Comparison of the concentrations of polychlorinated biphenyls and dioxins in mothers affected by the Yusho incident and their children

Accumulated maternal dioxins are passed onto the fetus and neonate via the placenta and maternal milk. In Japan in 1968, an accidental human exposure to rice oil contaminated with polychlorinated biphenyls (PCBs) and other dioxin-related compounds, such as polychlorinated dibenzofurans (PCDFs), led to development of Yusho oil disease. We investigated differences in blood dioxin concentrations in mother-children pairs affected by the Yusho incident. From 2002 to 2008, blood samples were collected from 26 pairs of Yusho mothers and their children (19 mothers, 26 children). Specific congeners of seven polychlorinated dibenzo-p-dioxins (PCDDs), ten PCDFs, and four non-ortho PCBs were analyzed. The children had significantly lower TEQ concentrations of PCDDs, PCDFs, and coplanar PCBs compared to their mothers. The mother-child difference in blood concentrations varied with the congeners; the largest for 2,3,4,7,8-pentaCDF and the smallest for 1,2,3,4,6,7,8-heptaCDD. The level for 2,3,4,7,8-pentaCDF, which characterizes Yusho oil disease, was approximately 17-30 times higher in the mothers than in the general population, whereas there were no significant differences between children in the formula-fed group and the general population. In contrast, the mean level for 2,3,4,7,8-pentaCDF in the breast-fed group was approximately 1.5 times, (range 0.5-6.5 times) higher than that in the general population. Over 30 years after the Yusho incident, the mean blood dioxin levels in the offspring were only a fraction of the levels in their mothers. This is more consistent with exposure via breast milk than via transplacental transfer in the Yusho incident.     

Direct observation of microcirculatory parameters in rat brain after local exposure to radio-frequency electromagnetic field

A cranial window method modified for our experiment enabled to observe the cerebral microcirculation including the blood-brain barrier permeability after a local expose to radio-frequency electromagnetic fields with a monopole antenna in rats. The present report reviews our recent publications that reported no noticeable changes in the cerebral microcirculatory parameters due to RF-EMF exposure.     

Aircraft and road traffic noise exposure and children's mental health

There have been few studies examining noise and psychological disorders in children and the results are equivocal. The objective of this study was to examine exposure–effect relationships between aircraft and road traffic noise exposure and children's mental health. We conducted a cross-national, cross-sectional study assessing 2844 pupils, aged 9–10, from 89 schools around three major airports in the Netherlands, Spain and United Kingdom matched within country for socio-economic position. We selected children on the basis of exposure to external aircraft and road traffic noise exposure. The Strengths and Difficulties Questionnaire (SDQ) assessed child mental health, including emotional problems, conduct disorder, hyperactivity, peer problems and prosocial behaviour. Aircraft noise exposure was significantly associated with an increased score on the hyperactivity subscale (pooled B estimate 0.013 CI 0.007–0.019) after full adjustment. Road traffic noise was significantly associated with lower scores on the conduct problems subscale maintained after full adjustment (pooled B estimate 0.010 95%CI −0.020 to −0.001). There was no association between either aircraft or road traffic noise exposure and the SDQ total score. The hyperactivity results have been found in a previous UK study and may indicate that high aircraft noise exposure exacerbates hyperactivity symptoms in children although this finding requires further replication.     

Resistance of pulmonate snail populations to repeated treatments of copper sulfate

Two species of pulmonate snails,Lymnaea cat-ascopium andPhysa integra, were collected from Douglas and Houghton Lakes. Snail populations from the former lake (pristine) had never been exposed to copper sulfate, whereas those from the latter one (treated) had been subjected to the molluscicide for more than 40 years. Molluscs from the treated lake were more resistant to the copper at concentrations of 0.5 and 1.0 ppm than those from the pristine lake. Furthermore, larger lymnaeids had a higher survival rate than smaller ones.     

PRELIMINARY STUDIES IN THE TERRESTRIAL DISPOSITION OF SILVER FROM CLOUD SEEDING1

ABSTRACT. Silver iodide is currently the most favored cloud seeding material in weather modification projects. While the literature indicates that its ecological effects are likely to be insignificant, its disposition in the terrestrial ecosystem after snow melt has not been adequately studied. Silver levels in soil, plant and litter material are being monitored twice a year on a mountainous area in southwestern Colorado, to determine whether annual accretion from cloud seeding can be measured with current techniques and whether significant changes in silver concentration take place in grass, aspen, and spruce communities. One AgI generator site is also being monitored. Comparison of silver concentrations in terrestrial components of the target area indicates no measurable increase after the first winter's seeding. On an ash basis, spruce foliage and litter contain about four times as much silver as soil. On a dry weight basis, soil from all three plant communities contains about six times as much silver as foliage. Consistent increases in silver concentration were found in soil and pine foliage within 200 meters of one generator site.